Defender Casey Stoney, 23; midfielders Katie Chapman, 23 and Jo Potter, 21; are joined by strikers Eniola Aluko, 19 and Amanda Barr, 23.
The match at Ewood Park kicks off at 7.05pm and is being screened live on BBC3. England's group is delicately poised with only the team that finishes top making it through to the Finals in China next year.
Source: The Football Association